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Always Powder Coating Pty Ltd
Cleaner Production
- Phosphate Pre-treatment of Steel

Always Powder Coating has replaced its conventional iron phosphate pre-treatment system with an organic process that operates at room temperature. The savings from reduced energy, labour and waste disposal costs amount to $60,000 per annum.

Background

Always Powder Coating (APC) operates a powder coating facility in Melbourne's eastern suburbs and specialises in powder coating of metal chair frames, bike frames and other similar metal components. An important part of powder coating is the cleaning and pre-treatment of the metal. Cleaning is required to remove residual oil and dirt, and phosphate pre-treatment is commonly used to enhance paint adhesion and corrosion resistance. This case describes APC's success in installing a phosphate treatment system using ECOPHOR A/477as a substitute for trichloroethylene. The ECOPHOR A/477 was supplied by Australian Chemicals and Coatings (ACC). 

The Process

The most common iron phosphating system uses a multi-stage water-based process. In the case of small items, this involves hanging the parts on racks or hooks suspended from an overhead conveyor. The parts then pass through the phosphating machine, where various solutions are sprayed over the parts. The process usually consists of the following distinct stages:

The solutions are recirculated through storage tanks located next to each stage. Some of the solutions require heating to approximately 60 degrees Celsius. There is significant sludge generation associated with the iron phosphating solution, which necessitates frequent desludging of the tank. In addition, all the solutions require periodic dumping, make-up water is required to replace evaporation losses, and there is a continuous overflow from the rinse stages.

In some operations, solvent-based (usually trichloroethylene) vapour degreasing systems replace the need for an alkaline degreasing stage. Vapour losses from such systems can be quite high, and even when totally enclosed there will still be some vapour loss.

Cleaner Production Initiative

APC has installed a phosphate treatment system that uses an organic phosphating process. The system uses a single solution of ECOPHOR A/477 that acts to both degrease the parts and provide a phosphate coating. The ECOPHOR solution is based on an inorganic polyphosphate dissolved in a low toxicity organic solvent medium. The solution has a very low vapour pressure and is therefore suited to conventional spray application.

The ECOPHOR solution works by initially degreasing the work piece and then depositing a thin layer of iron phosphate. A film forming polymer is deposited co-currently, and this is chemically linked with the metal via the phosphate. This polymer has the ability to absorb oils and greases, thus allowing the solution to be used continuously, without any requirement for periodic dumping. Degreasing of the metal surface, with the aid of the organic solvent, is followed by the adsorption of the oils and greases by the polyphosphate. The polyphosphate polymer will absorb a maximum of 6 per cent of its weight in oils and greases. This represents an average oil loading of 1.5 grams per square metre of treated metal surface. The final structure of the organic polyphosphate surface comprises a very thin layer of amorphous organic modified iron phosphate covered by a polymeric film. This is in contrast to a conventional phosphate process that produces a porous phosphate coating.

Heat curing is required to set the phosphate coating, as it is this process that drives off the remaining solvent and causes the free acid groups in the polymer to react with the substrate to produce a three dimensional structure.

The ECOPHOR solution can be applied by either spray (overhead conveyor) or dip techniques. Both systems have been installed by APC. Small parts (chair frames, etc.) are processed through a tunnel, which comprises a single ECOPHOR application, followed by an air knife to remove excess solution, and finally a curing oven. Large parts are treated in a converted vapour degreasing tank, where the solution is simply sprayed over the part, which is then oven cured. In both systems the parts are sprayed with the ECOPHOR solution for 60 seconds, followed by drying at 90-120 degrees Celsius for between 4 - 6 minutes.

Although the spray system equipment is similar in appearance to a conventional iron phosphating tunnel there are a number of differences that are critical to the successful operation of the system, including:


The solutions are tested fortnightly for oil content, resin content (polymer) and phosphoric acid. Additions are made where required. This is in contrast to a conventional phosphate process where rigorous process control testing is required (at least once daily).

Spray System Equipment

Spray System Equipment

Advantages of the Process

The adoption of this process has eliminated the generation of wastes normally associated with phosphate treatment systems. This has led to considerable savings. The benefits of the system to APC have been:

ECONOMIC BENEFITS

Total Capital Cost $177,800*
Annual Savings  
Chemical Costs $6,000
Waste Treatment $4,000
Reduced Energy Costs $20,000
Labour Savings $30,000
Total Annual Savings $60,000
Payback Period 2.8 years

* includes capital cost for tunnel and curing oven

This process is capable of treating a range of different metals, including steel, aluminium and aluminium alloys, cast iron and galvanised steel. Improved corrosion protection, in comparison with conventional iron phosphating without a chrome passivating stage, is achieved in salt spray tests (200-250 hours versus 100 hours).

Cleaner Production Incentive

The significant issue in adopting this process was that APC was reluctant to install a conventional phosphating system due to the problems associated with:

Barriers

There was some initial scepticism about the ability of the new process to provide a quality phosphate coating. This has been overcome and APC is now coating components for a number of high profile companies that have strict quality requirements.

Another potential barrier to uptake of the ECOPHOR system was the higher upfront chemical cost. The initial chemical cost was approximately $8,500, compared to $500 for an iron phosphate system. This high initial cost has, however, been offset by the benefits, including lower annual chemical costs, reduced energy usage, reduced trade waste generation and elimination of sludge disposal.

Further Developments

APC is one of a number of customers of Australian Chemicals and Coatings who have chosen ECOPHOR to replace  trichloroethylene vapour degreasing. For example, analytical equipment manufacturer Varian has been using an ECOPHOR A/447 pretreatment machine since 1996 and achieved a 63% cost saving on its previous $54,000 pa costs of vapour degreasing and etch priming. Benefits for Varian compared to the old system have been similar to those achieved by APC,  especially improved paint adhesion and corrosion resistance which is especially important for instruments in harsh environments. 

APC has continued to benefit from the initiative described in this case study although at the time of the  2001 case it was reviewing its pre-treatment processes in the light of alternative general purpose chemicals now available.

Contact

Ihab Bana
Always Powder Coating Pty Ltd
9 Gatwick Rd
Bayswater North
Victoria 3153
Ph: 61 3 9761 4666
Fax: 61 3 9761 4899
 
Mr Gavin Connelly
Australian Chemicals and Coatings Pty Ltd
69 Quantum Close
Dandenong
South Victoria 3175
Ph: 61 3 9799 9833
Fax: 61 3 9799 9033
Web Site: www.auschem.com.au
Email: gavin@auschem.com.au
Date of implementation: 1995
Date of further initiatives: Ongoing
Case study prepared: January 1997 by ACCP 
Date last modified: June 2001.
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